Annual composites of derived carbonate chemistry data collected at fixed stations by year.

Derived_Annual_Carbonate

Format

A dataframe

year

The year in which data was collected

station_name

The name of the station where data was collected

depth_m

The depth at which data was collected (metres)

mean_TA_umolkg

annual mean per section_name and depth_m of total alkalinity in umol/kg

mean_DIC_umolkg

annual mean per section_name and depth_m of dissolved inorganic carbon in umol/kg

mean_pH_total

annual mean per section_name and depth_m of pH on a total scale

mean_pCO2_uatm

annual mean per section_name and depth_m of pCO2 in uatm

mean_substrate_inhibitor_ratio

annual mean per section_name and depth_m of substrate-inhibitor ratio (mol/umol)

mean_omega_aragonite

annual mean per section_name and depth_m of the saturation state of omegaAragonite (unitless)

mean_omega_calcite

annual mean per section_name and depth_m of the saturation state of omega calcity (untiless)

mean_carbonate_system_vulnerability_index

annual mean per section_name and depth_m of Carbonate System Vulnerability Index (TA − DIC) (µmol/kg).

Details

Data collection and analysis was led by Kumiko Azetsu-Scott and data calculations were done by Martine Lizotte. Annual means are LS-means by year from linear models. If all values of a variable are positive in a section, a log10 model is used and back transformed. If any value is non-positive a linear model is used on the original scale. season and station_name are included in the model when they have >1 levels in that section. All missing values are replaced by -999.

More details on calculation methodology can be found in Lizotte, M., Blais, M., Chassé, J., Galbraith, P. S., Hébert, A.-J., Starr, M. 2026. Acidification and CO2-Driven Conditions in the Estuary and Gulf of St. Lawrence During 2024. Can. Tech. Rep. Hydrogr. Ocean. Sci. 0000 : v + x p. (in publication)